It is possible that it is Pierce disease. https://www.gardeningknowhow.com/edible/fruits/grapes/preventing-pierces-disease.htm
If you know that the area of the vines is being exposed regularly to the vapors from the hot tub and the unaffected vine is not then I’d suggest that that is the more likely problem. If the hot tub water is soaking into the soil, then that will definitely cause problems for the grapes. Also make sure that you aren’t overwatering them…this also can cause problems. Never spray water them…wet the soil, never the leaves.